Low Pressure Catalytic Combustion of Hydrogen on Palladium

نویسندگان

  • Xi Wang
  • Yixiang Shi
  • Ningsheng Cai
  • Xiaocheng Lv
  • Wei Yao
چکیده

Exhausts of airship fabric bag in the stratosphere such as hydrogen which can be used for fuels by using catalytic combustion method. This can save the extra fuels used in the power system. Pd/γAl2O3 catalyst was prepared in this work by impregnation method and the H2 catalytic combustion reaction kinetic was investigated between the pressure of 3.6 kPa and 101.3 kPa. The effects of temperature, pressure and gas composition ratio were studied in the paper. According to the experiment results, the increase of temperature increases the H2 conversion. The parameter pressure has a positive effect on H2 reaction kinetics and low concentration of H2 in mixtures shows better performance. The dependence of temperature on H2 reaction rate becomes more sensitive in high pressure.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis of nanostructured palladium, palladium oxide and palladium-palladium oxide nanocomposite by the gel combustion method and application as catalyst of hydrogen release

This paper presents a new gel combustion method to synthesize palladium nanoparticles, palladium oxide (PdO) nanoparticles and palladium-palladium oxide nanocomposites. In the proposed method, there are some effective parameters including palladium chloride concentration, polyvinyl alcohol (PVA) concentration, acid concentration, solvent composition and combustion temperature that their values ...

متن کامل

Multi-walled carbon nanotubes supported palladium nanoparticles: Synthesis, characterization and catalytic activity towards methanol electro oxidation in alkaline media

Palladium nanoparticles supported on multi-walled carbon nanotubes (Pd/MWCNTs) have been synthesized using a modified polyol reduction method and its performance in methanol oxidation reactions has evaluated. The morphology of palladium on MWCNTs was characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The catalytic performance of synthesized catalyst ...

متن کامل

Palladium composite membrane with high reversibility of CO2 poisoning

A palladium membrane was prepared using the electroless plating technique (ELP) for the separation and purification of hydrogen from a gas mixture. Depending on operating conditions, hydrogen flux from the membrane was in the range of 0.012-0.023 mol.m-2.s-1. The membrane performance in the presence of CO2 was investigated. The results of the GC analysis showed that at a feed concentration of 1...

متن کامل

Palladium nanoparticles supported on carbon black powder as an effective anodic catalyst for application in a direct glucose alkaline fuel cell

Palladium nanoparticles supported on carbon black powder (Vulcan XC-72) nanocomposite (Pd/C) are synthesized as the catalyst for the anodic oxidation of glucose for use in a direct glucose alkaline fuel cell (DGAFC). Characterization of the catalyst is carried out using physical and electrochemical methods. It is observed that Palladium nanoparticles are uniformly dispersed onto the carbon blac...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2015